浅议物理实验教学环节改革

为进一步提高大学物理实验的教学质量，本文就实验课的预习、操作、实验报告的撰写及考核方法进行了探讨。     

AN EFFECTIVE APPROACH FOR TWO-DIMENSIONAL POLARONS IN AN ASYMMETRIC QUANTUM DOT

Within the framework of Feynman-Haken path integral theory, we calculate the ground-state energy of two-dimensional polarons in asymmetric quantum dots for arbitrary electron-phonon coupling constants. From a general three-dimensional Hamiltonian, some interesting problems, such as polarons in quasi-one-dimensional quantum wires and quasi-zero-dimensional asymmetric or symmetric quantum dots can be easily discussed only by taking different limit in the whole coupling regime. After the numerical calculation, we find that the relative polaronic correction increases monotonically with the decrease of effective dot size, and it becomes more pronounced with increasing dimension and asymmetry. Moreover, despite the insensitivity of relative polaronic enhancement to the variation of coupling constant at weak coupling, the correction is related to the coupling constant as the latter becomes larger.     

An experimental investigation of high permittivity dielectric resonators for millimeter-wave microstrip components

This paper proposes a new type of high permittivity whispering gallery mode cylindrical dielectric resonators with a geometry which is very suitable for use in microstrip type integrated circuits. These oversized resonators, together with high Q factors and ease of fabrication, are potentially interesting for millimeter wave integrated filters and oscillators. In this paper, we report an experimental investigation of such resonators carried out in Ka band (26.5–40 GHz). Measured results including resonant frequencies and loaded quality factors will be presented. Application to millimeter wave filters will also be demonstrated.     

ZnCuCoAlNO3型四元水滑石及其多氧阴离子柱撑物的合成与催化氧化性能

Anionic clay, ZnCuCoAlNO₃ and its polyoxometalate intercalates were synthesized, and were characterized by XRD, IR, ³¹PMAS NMR, DTA and elemental analysis. The pillared products are found to be effective catalysts for oxidation of cyclohexene with molecular oxygen under mild reaction conditions     

Cyanex272-P507浸渍树脂协同萃取色层分离铥镱镥的研究

以Cyanex272-P507浸渍树脂采用萃取色层法对铥镱镥富集物进行了吸附和淋洗分离研究,考察了淋洗剂浓度、稀土负载量、淋洗液流速等因素对分离铥镱镥富集物的影响。结果表明,在充填的树脂粒度为0.3~0.6 mm的色层柱中,以0.2 ml.cm-2.min-1进料流速时能得到较大的吸附率;在稀土负载量为树脂重量的0.6%,淋洗液流速为1.0 ml.cm-2.min-1,温度为30℃,装柱树脂高度为400 mm(高径比为25∶1)的条件下,用1.0,1.5,2.0 mol.L-1盐酸梯度淋洗Tm,Yb,Lu,可实现铥镱镥富集物三者的完全分离。     

1β—Methyl Carbapenem中间体的合成

综述了１β－Ｍｅｔｈｙｌ Ｃａｒｂａｐｅｎｅｍ中间体的合成方法，重点强调了如何构筑１位β构型的甲基。参考文献３７篇。     

Determination of terbutaline with ferrocene-gold colloid-1,4-benzenedimethanethiol layer-by-layer self-assembled gold electrode

Aminylferrocene is successfully immobilized on nanosized gold colloid particles associated with a 1,4-benzenedimethanethiol monolayer on a gold electrode surface and characterized by cyclic voltammograms and electrochemical impedance spectroscopy. In a pH 7.0 phosphate buffer solution, the formal potential (E ⁰’) of Fc is 0.432 V (SCE), and the apparent surface electron-transfer rate constant is 0.89 s⁻. The immobilized Fc gives an excellent electrocatalytic response to the terbutaline oxidation. The catalytic-current response of differential pulse voltammograms increases linearly with the terbutaline concentration from 1.75 × 10⁻⁷ to 5.62 × 10⁻⁴ mol/l. The detection limit is 2.30 × 10⁻⁸ mol/l. The determination of terbutaline in a tablet dosage is satisfactory. The method is simple, quick, and sensitive. Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 8, pp. 969–974. The text was submitted by the authors in English.     

锌试剂分光光度法测定壳聚糖含量

利用锌试剂与壳聚糖在一定酸度条件下的特异性显色反应，即其复合物在465nm处吸光度与壳聚糖含量在0～O．04g／L范围内呈现良好的线性关系(R=0．996)，基于此建立了一种简便快速的分光光度法。平均回收率为99．68％。     

原子转移自由基聚合原位合成温敏性微球

以过硫酸钾为引发剂、丙酮-水[V(丙酮)∶V(水)＝4∶6]的混合溶剂为反应介质, 在少量二乙烯苯存在的条件下使苯乙烯(St)和对氯甲基苯乙烯(CMSt)进行无皂乳液共聚反应, 得到了粒径大小均匀的交联型聚苯乙烯(PSt)微球, 由X射线光电子能谱对表面组分测定发现: CMSt上的氯原子在聚合过程中富集于交联微球的表面. 以此交联型PSt微球为原子转移自由基聚合(ATRP)的引发剂, 在22 ℃下引发N-异丙基丙烯酰胺(NIPAAm)进行原位ATRP反应, 得到了表面原子转移自由基聚合接枝的交联聚苯乙烯(PNIPAAm-g-PSt)温敏性微球. 借助傅立叶变换红外光谱、差示扫描量热仪、扫描电子显微镜及激光光散射仪等对PNIPAAm-g-PSt的结构、相转变温度、形态及不同温度下的粒径变化进行了测定, 结果表明NIPAAm单体成功地原位ATRP接枝在交联PSt微球的表面, 接枝微球的球形更规整, 在水中的相转变温度约为32 ℃, 具有明显的温度敏感性.